EFFICIENT CARBON-DIOXIDE PHOTOREDUCTION BY NOVEL METAL-COMPLEXES AND ITS REACTION-MECHANISMS

被引：10

作者：

HORI, H ^{[1
]}

ISHITANI, O ^{[1
]}

KOIKE, K ^{[1
]}

JOHNSON, FPA ^{[1
]}

IBUSUKI, T ^{[1
]}

机构：

[1] NATL INST RESOURCES & ENVIRONM,PHOTOENERGY APPLICAT LAB,TSUKUBA,IBARAKI 305,JAPAN

来源：

ENERGY CONVERSION AND MANAGEMENT | 1995年 / 36卷 / 6-9期

关键词：

D O I：

10.1016/0196-8904(95)00082-O

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Photoreduction of CO2 to CO using the new catalysts, [Re(bpy)(CO)(3){P(OEt)(3)}](+) (1(+)) and [Re(bpy)(CO)(3)(PPh(3))](+) (2(+)) is described. The quantum yields of CO formation are 0.23 and 0.05 for 1(+) and 2(+), respectively. The value for 1(+) is one of the highest reported values for homogeneous CO2 reduction photocatalysts. In-situ UV/vis spectra indicate that one-electron reduced species is an important intermediate.

引用

页码：621 / 624

页数：4

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