KINETICS OF CHLORINE ATOM REACTION WITH HYDROGEN BROMIDE

被引：10

作者：

DOBIS, O ^{[1
]}

BENSON, SW ^{[1
]}

机构：

[1] UNIV SO CALIF,LOKER HYDROCARBON RES INST,LOS ANGELES,CA 90089

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 14期

关键词：

D O I：

10.1021/j100014a019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of reaction Cl + HBr -->/1 HCl (v) + Br have been studied at 298 K using the very low pressure reactor (VLPR). k(1) = (6.16 +/- 0.07) x 10(-12) cm(3)/(molecule s), Calculated from both the reactant consumption and Br product formation rate measurements. Mass conservation is found to be 97 +/- 3% for the overall chemical change in the system. Calculations using known relaxation rates for HCl (v) show that vibrationally excited products of either HCl (v=2) or HBr (v=1) have no measurable contribution to the kinetics of reaction 1 under the steady-state flow conditions in the VLPR system.

引用

页码：4986 / 4991

页数：6

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