STRUCTURAL TRANSITIONS IN A TINIFE SHAPE-MEMORY ALLOY

被引:6
|
作者
MARQUINA, ML [1 ]
JIMENEZ, M [1 ]
MARQUINA, V [1 ]
ABURTO, S [1 ]
RIDAURA, R [1 ]
GOMEZ, R [1 ]
ESCUDERO, R [1 ]
RIOSJARA, D [1 ]
机构
[1] Univ Nacl Autonoma Mexico, INST INVEST MAT, 04510 MEXICO CITY, DF, MEXICO
关键词
D O I
10.1016/1044-5803(94)90088-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Results for resistance versus temperature, differential scanning calorimetry (DSC), Mossbauer spectroscopy, and magnetic susceptibility measurements in a Ti50Ni47Fe3 sample are presented. The resistance versus temperature curve shows a sharp increase at 245K and then rises slowly until a maximum is attained at almost-equal-to 150K. The DSC curve also exhibits a peak at the former temperature. The room temperature Mossbauer spectrum consists of a single line. As the temperature is lowered to 270K, a small asymmetric quadrupole doublet appears. The isomer shift and quadrupole splitting values of this doublet increase with decreasing temperature until almost constant values are achieved at temperatures almost-equal-to 100K. The magnetic susceptibility curve shows a sharp decrease that begins at 255K and then an unexpected increase at 90K. We relate these observations with a charge density wave-driven premartensitic transition in this system, and with the final martensitic phase.
引用
收藏
页码:189 / 193
页数:5
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