HOMOGENEOUS HYDROGENATION OF CARBON-DIOXIDE WITH TRANSITION-METAL COMPLEXES

被引：3

作者：

IKARIYA, T

JESSOP, PG

TOKUNAGA, M

NOYORI, R

机构：

[1] ERATO Molecular Catalysis Project, JRDC

[2] Department of Chemistry, Faculty of Science, Nagoya University

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1994年 / 52卷 / 12期

关键词：

CARBON DIOXIDE; CATALYTIC REDUCTION; HOMOGENEOUS HYDROGENATION; TRANSITION METAL COMPLEX; SUPERCRITICAL FLUID; FORMIC ACID; METHYL FORMATE; N; N-DIMETHYLFORMAMIDE;

D O I：

10.5059/yukigoseikyokaishi.52.1032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent advances in the efficiency of the homogeneous catalytic reduction of carbon dioxide may bring CO2 fixation by this method from a research curiosity into an industrially applicable process. The reduction of CO2 to bulk chemicals such as dimethylformamide, methyl formate, and methanol offers a safer alternative to toxic CO-based processes. This review describes stoichiometric and homogeneously catalyzed reactions of CO2, especially those which involve hydrogenation by hydrogen gas. The newly discovered advantages of supercritical CO2 as a medium for its own fixation will be particularly highlighted.

引用

页码：1032 / 1043

页数：12

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