CONVENIENT AND SHORT ROUTE TO A KEY INTERMEDIATE IN THE SYNTHESIS OF FORSKOLIN

被引：3
|
作者：
BACIGALUPPO, JA [1 ]
COLOMBO, MI [1 ]
ZINCZUK, J [1 ]
HUBER, SN [1 ]
MISCHNE, MP [1 ]
RUVEDA, EA [1 ]
机构：
[1] UNIV NACL ROSARIO,CONSEJO NACL INVEST CIENT & TECN,FAC CIENCIAS BIOQUIM & FARMACEUT,RA-2000 ROSARIO,ARGENTINA
来源：
SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 12-13期
关键词：
D O I：
10.1080/00397919108021283
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The intermediate 2, previously used in several synthetic sequences toward forskolin (1), has been synthesized from enone 3. The key step in the sequence is the 1,3-oxidative rearrangement of the tertiary alcohol 5, which allowed the easy introduction of the keto group at C-6 of 2.
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页码：1361 / 1367
页数：7
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