PREPARATION AND CATALYTIC PROPERTY OF L-HISTIDYL GROUP-INTRODUCED, CROSS-LINKED POLY(ETHYLENE IMINE)S IMPRINTED BY A TRANSITION-STATE ANALOG OF AN ESTEROLYSIS REACTION

被引：33

作者：

OHKUBO, K

URATA, Y

HONDA, Y

NAKASHIMA, Y

YOSHINAGA, K

机构：

[1] KUMAMOTO UNIV,FAC ENGN,DEPT APPL CHEM,KUMAMOTO 860,JAPAN

[2] KYUSHU INST TECHNOL,DEPT APPL CHEM,KITAKYUSHU 804,FUKUOKA,JAPAN

来源：

POLYMER | 1994年 / 35卷 / 24期

关键词：

IMPRINTED POLYMER; CATALYST; MOLECULAR RECOGNITION;

D O I：

10.1016/0032-3861(94)90494-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A crosslinked, L-histidyl group-introduced polymer catalyst, which was imprinted by a transition-state analogue of phenyl 1-benzyloxycarbonylamino-3-methylpentylphosphonate in the hydrolysis of p-nitrophenyl N-carbobenzoxy-L-leucinate, was prepared from poly(2-methyl-2-oxazoline). The catalyst enhanced the hydrolysis of the L-leucine ester, in comparison to the hydrolysis of the L-phenylalanine and L-alanine esters.

引用

页码：5372 / 5374

页数：3

共 2 条

[1] Preparation and catalytic property of L-histidyl group-introduced, crosslinked poly(ethylene imine)s imprinted by a transition-state analogue of an esterolysis reaction
Ohkubo, Katsutoshi
Urata, Yasuo
Honda, Yuhji
Nakashima, Yasuhiro
Yoshinaga, Kohji
Polymer, 1994, 35 (24): : 5372 - 5374
[2] CATALYTIC ACTIVITIES OF NOVEL L-HISTIDYL GROUP-INTRODUCED POLYMERS IMPRINTED BY A TRANSITION-STATE ANALOG IN THE HYDROLYSIS OF AMINO-ACID ESTERS
OHKUBO, K
URATA, Y
HIROTA, S
FUNAKOSHI, Y
SAGAWA, T
USUI, S
YOSHINAGA, K
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 101 (02) : L111 - L114

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