INSECT PHEROMONE SYNTHESIS USING MN-SALEN CATALYZED ASYMMETRIC EPOXIDATION AS A KEY STEP

被引：34

作者：

HAMADA, T ^{[1
]}

DAIKAI, K ^{[1
]}

IRIE, R ^{[1
]}

KATSUKI, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 81281,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 10期

关键词：

D O I：

10.1016/0957-4166(95)00319-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantioselective synthesis of three insect pheromones, (5Z, 13S)-5-tetradecen-13-olide, (9R)-decan-9-olide, and (S)-2-acetoxytridecane, has been achieved by using Mn-salen catalyzed asymmetric epoxidation as a key step.

引用

页码：2441 / 2451

页数：11

共 50 条

[31] Convenient asymmetric (salen)Mn(III)-catalyzed epoxidation of unfunctionalized alkenes with hydrogen peroxide using carboxylate salt cocatalysts
Pietikäinen, P
TETRAHEDRON, 1998, 54 (17) : 4319 - 4326
[32] Covalently functionalized carbon nanoparticles with a chiral Mn-Salen: a new nanocatalyst for enantioselective epoxidation of alkenes
Zammataro, Agatino
Gangemi, Chiara Maria Antonietta
Pappalardo, Andrea
Toscano, Rosa Maria
Puglisi, Roberta
Nicotra, Giuseppe
Fragala, Maria Elena
Tuccitto, Nunzio
Sfrazzetto, Giuseppe Trusso
CHEMICAL COMMUNICATIONS, 2019, 55 (36) : 5255 - 5258
[33] Asymmetric epoxidation of unfunctionalized olefins catalyzed by Mn(III) salen complex immobilized on MCM-48
Yu, Kai
Lou, Lan-Lan
Lai, Chao
Wang, Shengjie
Ding, Fei
Liu, Shuangxi
CATALYSIS COMMUNICATIONS, 2006, 7 (12) : 1057 - 1060
[34] Asymmetric epoxidation of chromene derivatives with hydrogen peroxide catalyzed by optically active Mn(III) salen complex
Sun, HB
Hua, WY
Peng, SX
CHINESE CHEMICAL LETTERS, 1995, 6 (11) : 927 - 930
[35] The effect of phenolates in the (salen)Mn-catalyzed epoxidation reactions
Linde, C
Anderlund, MF
Åkermark, B
TETRAHEDRON LETTERS, 2005, 46 (33) : 5597 - 5600
[36] Enantioselective epoxidation of 2,2-dimethylchromenes using achiral Mn-Salen complex as a catalyst in the presence of chiral amine
Hashihayata, T
Ito, Y
Katsuki, T
SYNLETT, 1996, (11) : 1079 - &
[37] Asymmetric Epoxidation of Unfunctionalized Olefins Catalyzed by Chiral (Pyrrolidine Salen) Mn (III) Complexes with Proline Sidearms
Han, Dong
Li, Yuanfeng
Han, Ya-Ping
Zhang, Hong-Yu
Zhang, Yuecheng
Zhao, Jiquan
MOLECULAR CATALYSIS, 2022, 524
[38] Epoxidation of cyclohexene catalyzed by Mn (salen) complex in ionic liquids
Tao Liang
Yin Donghong
Tan Rong
Yu Ningya
Yin Dulin
CHINESE JOURNAL OF CATALYSIS, 2006, 27 (05) : 440 - 444
[39] Is there a radical intermediate in the (salen)Mn-catalyzed epoxidation of alkenes?
Linde, C
Arnold, M
Norrby, PO
Akermark, B
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (16): : 1723 - 1725
[40] ASYMMETRIC EPOXIDATION USING CHIRAL SALEN COMPLEXES
IRIE, R
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1993, 51 (05) : 412 - 420

← 1 2 3 4 5 →