INFLUENCE OF COMPOSITION ON PROPERTIES OF HYDROGELS OF 2-HYDROXYETHYL METHACRYLATE WITH A SULFOBETAINE COMONOMER

被引：25
|
作者：
REGO, JM [1 ]
HUGLIN, MB [1 ]
机构：
[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,SALFORD M5 4WT,LANCS,ENGLAND
来源：
POLYMER JOURNAL | 1991年 / 23卷 / 12期
关键词：
2-HYDROXYETHYL METHACRYLATE; ZWITTERIONIC METHACRYLATE; COPOLYMER; HYDROGEL; SWELLING; MICROSTRUCTURE;
D O I：
10.1295/polymj.23.1425
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The copolymerization of 2-hydroxyethyl methacrylate (HEMA) and a zwitterionic methacrylate N,N-dimethyl-N-methacryloxyethyl-N-(3-sulphopropyl)-ammonium betaine in the presence of a tetrafunctional crosslinker has been effected to 100% conversion by gamma-irradiation. The resultant xerogels were swollen to equilibrium in water to yield hydrogels. The water uptake, types of water and the mechanical properties were examined and discussed with relation to the composition of the copolymer. The synergistic swelling behavior found has been explained on the basis of calculated microstructural composition.
引用
收藏
页码：1425 / 1434
页数：10
相关论文
共 50 条
  • [41] THE PHYSICAL PROPERTIES OF POLY(2-HYDROXYETHYL METHACRYLATE)COPOLYMER HYDROGELS USED AS INTRAVAGINAL RINGS
    Young A Han
    Eun Mi Lee
    Byung Chul Ji
    Chinese Journal of Polymer Science, 2009, 27 (03) : 359 - 366
  • [42] Equilibrium swelling properties of weakly ionizable 2-hydroxyethyl methacrylate (HEMA)-based hydrogels
    Baker, John P., 1600, Publ by John Wiley & Sons Inc, New York, NY, United States (52):
  • [43] Tribological Properties of Micropored Poly(2-hydroxyethyl methacrylate) Hydrogels in a Biomimetic Aqueous Environment
    Xi, Yiwen
    Sharma, Prashant Kumar
    Kaper, Hans Jan
    Choi, Chang-Hwan
    ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (35) : 41473 - 41484
  • [44] 2-HYDROXYETHYL METHACRYLATE
    KATO, M
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1992, 50 (10) : 926 - 927
  • [45] EQUILIBRIUM SWELLING PROPERTIES OF WEAKLY IONIZABLE 2-HYDROXYETHYL METHACRYLATE (HEMA)-BASED HYDROGELS
    BAKER, JP
    BLANCH, HW
    PRAUSNITZ, JM
    JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 52 (06) : 783 - 788
  • [46] HYDROGELS BASED ON COPOLYMERS OF N-(2-HYDROXYETHYL)METHACRYLAMIDE, 2-HYDROXYETHYL METHACRYLATE, AND 4-T-BUTYL-2-HYDROXYCYCLOHEXYL METHACRYLATE
    FRIENDS, G
    KUNZLER, J
    MCGEE, J
    OZARK, R
    JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 49 (11) : 1869 - 1876
  • [47] Hydrogels based on copolymers of N-(2-hydroxyethyl)methacrylamide, 2-hydroxyethyl methacrylate, and 4-t-butyl-2-hydroxycyclohexyl methacrylate
    Friends, G., 1869, Publ by John Wiley & Sons Inc, New York, NY, United States (49):
  • [48] Biological properties of copolymer of 2-Hydroxyethyl methacrylate with sulfopropyl methacrylate
    Lukás, J
    Smetana, K
    Petrovicky, P
    Palecková, V
    Vacik, J
    Dvoránková, B
    Broz, L
    Pospísilová, D
    Holíková, Z
    Bartunková, J
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2001, 12 (07) : 639 - 646
  • [49] Biological properties of copolymer of 2-Hydroxyethyl methacrylate with sulfopropyl methacrylate
    Jaromir Lukáš
    Karel Smetana
    Pavel Petrovický
    Věra Palečková
    Jiří Vacik
    Barbora Dvořánková
    Ludomír Brož
    Dagmar Pospíšilová
    Zuzana Holíková
    Jiřina Bartůňková
    Journal of Materials Science: Materials in Medicine, 2001, 12 : 639 - 646
  • [50] Preferential interactions of calcium ions in poly(2-hydroxyethyl methacrylate) hydrogels
    Zainuddin
    Hill, D. J. T.
    Whittaker, A. K.
    Lambert, L.
    Chirila, T. V.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2007, 18 (06) : 1141 - 1149
12345