INVESTIGATION OF ELECTROCHEMICAL AND CHEMICAL GUAIACOL OXIDATION-PRODUCTS

被引：0
|
作者：
VASILEVA, LV
SHCHUKIN, IV
BABKIN, VA
机构：
来源：
RUSSIAN ELECTROCHEMISTRY | 1993年 / 29卷 / 04期
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D O I：
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中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The products of direct and indirect (potassium ferrocyanide as a mediator) electrochemical guaiacol oxidation at a platinum electrode in alkaline solutions were studied and compared with the products of chemical guaiacol oxidation with potassium ferricyanide. The major oxidation products were shown to be vanillin, vanillic acid, acetoguaiacol, and oligomers produced by oxidative coupling. Possible reaction mechanisms were discussed.
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页码：609 / 615
页数：7
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