SESQUITERPENE PYRIDINE ALKALOIDS FROM MAYTENUS-CHUCHUHUASCA

被引:0
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作者
SHIROTA, O
OTSUKA, A
MORITA, H
TAKEYA, K
ITOKAWA, H
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O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Structural elucidations of seven novel sesquiterpene pyridine alkaloids, chuchuhuanines E-I (1), E-II (2), E-III (3), E-IV (4), E-V (5), W-I (6) and 4-deoxyeuonymine (7), which were isolated along with seven known alkaloids from root barks of Maytenus chuchuhuasca Raymond-Hamet et Colas (Celastraceae), are presented. Their structures with a novel dihydro-beta-agarofuran type sesquiterpene core, linking several ester moieties and including a fifteen or a sixteen membered macrocyclic diester ring system, were elucidated by mainly spectroscopic methods.
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页码:2219 / 2229
页数:11
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