SINGLE-CRYSTAL EPR SPECTROSCOPY ON [FE-57(NO)(S(2)CNET(2))(2)] - THE TRIPLET SIGNAL IN THE EPR-SPECTRUM OF [FE(S(2)CNET(2))(3)]

被引：6
|
作者：
KIRMSE, R
SALUSCHKE, S
MOLLER, E
REIJERSE, EJ
GELERINTER, E
DUFFY, NV
机构：
[1] KENT STATE UNIV, DEPT PHYS, KENT, OH USA
[2] KENT STATE UNIV, DEPT CHEM, KENT, OH USA
[3] UNIV NIJMEGEN, MOLEK SPEKT ABT, NIJMEGEN, NETHERLANDS
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 14期
关键词：
D O I：
10.1002/anie.199414971
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Traces of nitrate in the starting material FeCl3 lead to the formation of the analogous nitrosyliron(I) complex 2 during the synthesis of the tris(dithiocarbamato)iron complex 1. EPR studies on 57Fe‐labeled 2 show that this complex gives rise to the triplet signal in the EPR spin‐crossover studies on 1 at g = 2.0 that has been discussed for a long time. (Figure Presented.) (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码：1497 / 1499
页数：3
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