NEW ORGANIC NONLINEAR OPTICAL-CRYSTALS OF BENZYLIDENE-ANILINE DERIVATIVE

被引：51

作者：

TSUNEKAWA, T

GOTOH, T

IWAMOTO, M

机构：

[1] Electronic and Imaging Materials Research Laboratories, Toray Industries Inc., Otsu, Shiga, 520

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 166卷 / 04期

关键词：

D O I：

10.1016/0009-2614(90)85042-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The benzylidene-aniline derivative with an electron-donating group at the 4-position and an electron-accepting group at the 4′-position has been suggested, by MO calculations, to have a small molecular dipole moment in spite of the large second-order hyperpolarizability, and hence to be a promising molecule in the search for new organic crystals with large second-order optical non-linearity. By modification of the molecule suggested, a series of crystals having high second-harmonic generation (SHG) activities have been discovered; one of them showed a larger powder SHG than 2-methyl-4-nitroaniline (MNA). © 1990.

引用

页码：353 / 357

页数：5

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