POTASSIUM TRANSFER FACILITATED BY MONOAZA-18-CROWN-6 ACROSS THE WATER-1,2-DICHLOROETHANE INTERFACE

被引：16
|
作者：
TAN, SN [1 ]
GIRAULT, HH [1 ]
机构：
[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 332卷 / 1-2期
关键词：
D O I：
10.1016/0022-0728(92)80343-3
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The facilitated potassium transfer by monoaza-crown-6 (A18C6) across the water-1,2-dichloroethane interface has been investigated by cyclic voltammetry. The pH of the aqueous phase determines the nature of and the type of assisted ion transfer, i.e. proton transfer, assisted metal ion transfer or both. The stability constants of protonated A18C6 and potassium-A18C6 in 1,2-dichloroethane, and potassium-A18C6 in water, have been evaluated from the voltammetric data.
引用
收藏
页码：101 / 112
页数：12
相关论文
共 50 条
  • [31] Facilitated Ion Transfers at the Micro-Water/1,2-Dichloroethane Interface by Crown Ether Derivatives
    Qiao, Yonghui
    Zhang, Ben
    Zhu, Xinyu
    Ji, Tianrong
    Li, Bo
    Li, Qing
    Chen, Erqiang
    Shao, Yuanhua
    ELECTROANALYSIS, 2013, 25 (04) : 1080 - 1084
  • [32] Systematic investigation of alkali metal ion transfer across the micro- and nano-water/1,2-dichloroethane interfaces facilitated by dibenzo-18-crown-6
    Yuan, Y
    Shao, YH
    JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (32): : 7809 - 7814
  • [33] Electrochemical instability in the transfer of cationic surfactant across the 1,2-dichloroethane/water interface
    Kasahara, T
    Nishi, N
    Yamamoto, M
    Kakiuchi, T
    LANGMUIR, 2004, 20 (03) : 875 - 881
  • [34] Solvation Effect Facilitates Ion Transfer across Water/1,2-Dichloroethane Interface
    Nsabimana, Jacques
    Nestor, Uwitonze
    Girma, Girum
    Pamphile, Ndagijimana
    Zhan, Dongping
    Tian, Zhong-Qun
    CHEMELECTROCHEM, 2016, 3 (12): : 2165 - 2169
  • [35] ERYTHROMYCIN TRANSFER ACROSS THE WATER 1,2-DICHLOROETHANE INTERFACE MODIFIED BY A PHOSPHOLIPID MONOLAYER
    YUDI, LM
    SANTOS, E
    BARUZZI, AM
    SOLIS, VM
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 379 (1-2): : 151 - 158
  • [36] Oleic and nitro-oleic acid behavior at an electrified water-1,2-dichloroethane interface
    Sobczak, Karolina
    Rudnicki, Konrad
    Jedinak, Lukas
    Zatloukalova, Martina
    Vacek, Jan
    Poltorak, Lukasz
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 365
  • [37] Effect of phospholipids on the kinetics of dioxygen transfer across a 1,2-dichloroethane/water interface
    Strutwolf, J
    Zhang, J
    Barker, AL
    Unwin, PR
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (24) : 5553 - 5558
  • [38] Facilitated proton transfer by 2-acetylpyridine-4-phenyl-3-thiosemicarbazone across water/1,2-dichloroethane interface
    Benvidi, Ali
    Lanjwani, Shah Nawaz
    Ding, Zhifeng
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2010, 641 (1-2) : 99 - 103
  • [39] Voltammetric characterization of selective potassium ion transfer across micro-water/1,2-dichloroethane interface facilitated by a novel calix[4]arene derivative
    Durmaz, Muge
    Zor, Erhan
    Kocabas, Erdal
    Bingol, Haluk
    Akgemci, Emine G.
    ELECTROCHIMICA ACTA, 2011, 56 (15) : 5316 - 5321
  • [40] Cationic-surfactant transfer facilitated by DNA adsorbed on a polarized 1,2-dichloroethane/water interface
    Osakai, T.
    Komatsu, H.
    Goto, M.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (37)
12345