KINETIC EVIDENCE FOR THE SOLVENT INTERVENTION IN THE SOLVOLYSIS OF 2-ARYL-2-PROPYL PARA-NITROBENZOATES - ELECTRONIC AND STERIC EFFECTS

被引：32

作者：

LIU, KT

CHANG, LW

CHEN, PS

机构：

[1] Department of Chemistry, National Taiwan University, Taipei

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 18期

关键词：

D O I：

10.1021/jo00044a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Kinetic observation indicates significant nucleophilic solvent intervention at the cationic transition state in the solvolysis of 2-phenyl-2-propyl p-nitrobenzoate (1a).

引用

页码：4791 / 4793

页数：3

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