RATES OF SOLVOLYSIS OF 2-METHYL-2-PROPYL PARA-NITROBENZOATES, 2-TERT-BUTYL-2-PROPYL PARA-NITROBENZOATES, 2-PHENYL-2-PROPYL PARA-NITROBENZOATES, AND 2-CYCLOPROPYL-2-PROPYL PARA-NITROBENZOATES - EVIDENCE THAT C-13 CHEMICAL-SHIFTS OF CARBONIUM-IONS DO NOT CORRELATE WITH STABILITIES OF SOLVOLYTIC TRANSITION-STATES AND CORRESPONDING CATIONIC INTERMEDIATESB

被引：54

作者：

BROWN, HC ^{[1
]}

PETERS, EN ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB,LAFAYETTE,IN 47907

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1973年 / 95卷 / 07期

关键词：

D O I：

10.1021/ja00788a070

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2400 / 2402

页数：3

共 20 条

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[5] SOLVOLYSIS OF 2-(OMEGA-ALKOXYALKYL)-3-METHYL-2-CYCLOHEXENYL PARA-NITROBENZOATES - SEARCH FOR NEIGHBORING OXYGEN PARTICIPATION
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[6] SOLVOLYSIS OF 2-ARYL-5-METHYL-2-NORBORNENYL PARA-NITROBENZOATES - EVIDENCE FOR PI PARTICIPATION AS A FACTOR IN VARIATION OF RATES AND PRODUCTS WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER
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[7] BETA-DEUTERIUM KINETIC ISOTOPE EFFECTS IN THE SOLVOLYSIS OF 2-ARYL-1,1,1-TRIFLUORO-2-PROPYL TOSYLATES AND OF 2-ARYL-2-PROPYL PARA-NITROBENZOATES - EVIDENCE FOR A VARIATION OF THE CONTRIBUTION OF ALPHA-METHYL SUBSTITUENT IN STABILIZING CATIONIC REACTION CENTERS WITH DIFFERENT ELECTRON DEMAND
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[8] SOLVOLYSIS OF 2-ARYL-2-BICYCLO[2.1.1]HEXYL PARA-NITROBENZOATES - EVIDENCE FOR ABSENCE OF SIGMA-PARTICIPATION BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (26) : 7449 - 7453
[10] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .25. SOLVOLYSIS OF ARYL(2-NORBORNYL)METHYLCARBINYL PARA-NITROBENZOATES - SEARCH FOR A SPECIAL STEREOELECTRONIC EFFECT WITH TOOL OF INCREASING ELECTRON DEMAND
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