Stereochemistry of the electroreduction of the C-Cl bond

被引:14
|
作者
Czochralska, Barbara [1 ]
机构
[1] Univ Warsaw, Dept Biophys, Inst Inorgan Chem, Warsaw, Poland
关键词
D O I
10.1016/0009-2614(67)85062-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electroreduction mechanism of alpha-halogen derivatives of organic compounds in proton donating solvents was investigated on the exampie of optically active 2-phenyl-2-chloropropionic acid. It was shown that the electroreduction occurs with inversion of configuration according to the SN2 mechanism.
引用
收藏
页码:239 / 241
页数:3
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