Stereochemistry of the electroreduction of the C-Cl bond

被引：14
|
作者：
Czochralska, Barbara [1 ]
机构：
[1] Univ Warsaw, Dept Biophys, Inst Inorgan Chem, Warsaw, Poland
来源：
CHEMICAL PHYSICS LETTERS | 1967年 / 1卷 / 05期
关键词：
D O I：
10.1016/0009-2614(67)85062-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electroreduction mechanism of alpha-halogen derivatives of organic compounds in proton donating solvents was investigated on the exampie of optically active 2-phenyl-2-chloropropionic acid. It was shown that the electroreduction occurs with inversion of configuration according to the SN2 mechanism.
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收藏
页码：239 / 241
页数：3
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