Ethyl 1''-benzyl-1'-methyl-2''-oxodispiro[indeno[1,2-b]quinoxaline-11,3'pyrrolidine-2',3''-indoline]-4'-carboxylate

被引:1
|
作者
Kannan, Piskala Subburaman [1 ]
Lanka, Srinu [2 ]
Thennarasu, Sathiah [2 ]
Govindan, Elumalai [3 ]
SubbiahPandi, Arunachalathevar [3 ]
机构
[1] SMK Fomra Inst Technol, Dept Phys, Chennai 603103, Tamil Nadu, India
[2] CSIR, Cent Leather Res Inst, Organ Chem Div, Chennai 600020, Tamil Nadu, India
[3] Presidency Coll Autonomous, Dept Phys, Chennai 600005, Tamil Nadu, India
关键词
D O I
10.1107/S1600536813011525
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C36H30N4O3, the quinoxaline-indene system is roughly planar, with a maximum deviation from the mean plane of 0.218 angstrom for the C atom shared with the central pyrrolidine ring. This latter ring forms dihedral angles of 84.54 (7) and 83.91 (8)degrees with the quinoxaline-indene system and the indole ring, respectively. The central pyrrolidine ring has an envelope conformation with the N atom as the flap, while the pyrrolidine and five-membered rings of the indole group adopt twisted conformation and envelope (with the C atom bearing the quinoxaline-indene system as the flap) conformations, respectively. In the crystal, molecules are linked via weak C-H ... N hydrogen bonds, forming a chain running along [100].
引用
收藏
页码:O822 / +
页数:11
相关论文
共 50 条
  • [11] 3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4methylphenyl) spiro[pyrrolidine-2,11'-indeno[1,2-b] quinoxaline]
    Vijayakumar, B.
    Gavaskar, D.
    Srinivasan, T.
    Raghunathan, R.
    Velmurugan, D.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1274 - +
  • [12] 3'-Ferrocenylcarbonyl-1'-methyl-4'-phenylspiro[indeno[2,3-b] quinoxaline-11,2'-pyrrolidine]
    Vijayakumar, B.
    Gavaskar, D.
    Srinivasan, T.
    Raghunathan, R.
    Velmurugan, D.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1382 - +
  • [13] 1',1"- Dimethyl-4'-(4-methylphenyl)dispiro[11H-indeno[1,2-b]quinoxaline-11,2'-pyrrolidine-3',3"-piperidin]-4"-one
    Nagalakshmi, R. A.
    Suresh, J.
    Malathi, K.
    Kumar, R. Ranjith
    Lakshman, P. L. N.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1466 - +
  • [14] An efficient multicomponent and stereoselective synthesis of new spiro[indeno[1,2-b]quinoxaline-11,2′-pyrrolidine] derivatives
    Moemeni, Mehdi
    Arvinnezhad, Hamid
    Samadi, Saadi
    Tajbakhsh, Mahmood
    Jadidi, Khosrow
    Khavasi, Hamid Reza
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2012, 49 (01) : 190 - 194
  • [15] Crystal structure of 1 ',1 ''-dimethyl-4 '-(4-cholorophenyl)dispiro[11H-indeno[1,2-b]quinoxaline-11,2 '-pyrrolidine-3 ',3 ''-piperidin]-4 ''-one
    Nagalakshmi, R. A.
    Suresh, J.
    Malathi, K.
    Kumar, R. Ranjith
    Lakshman, P. L. Nilantha
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O68 - U258
  • [16] {1'-Phenyl-1',2',5',6',7',7a'-hexahydro-spiro[indeno[1,2-b]quinoxaline-11,3'-pyrrolizin]-2'-yl}(p-tolyl)methanone
    Srinivasan, T.
    Suhitha, S.
    Purushothaman, S.
    Raghunathan, R.
    Velmurugan, D.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02469 - +
  • [17] Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate
    Kamala, E. Theboral Sugi
    Nirmala, S.
    Sudha, L.
    Kathiravan, S.
    Raghunathan, R.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M531 - U653
  • [18] 1'-Methyl-4'-(4-methylphenyl)dispiro-[indane-2,3'-pyrrolidine-2',3''-indoline]-1,2''-dione
    Moustafa, A. M.
    Girgis, Adel S.
    Shalaby, S. M.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2197 - +
  • [19] Methyl 3'-benzyl-4'-(2-chlorophenyl)-1'-methyl-2-oxospiro[indoline-3,2'-pyrrolidine]-3'-carboxylate
    Anuradha, T.
    Devaraj, A.
    Seshadri, P. R.
    Bakthadoss, M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1214 - +
  • [20] Crystal structure of ethyl 1 ',1 ''-dimethyl-2 '',3-dioxo-3H-dispiro[benzo[b]thiophene-2,3 '-pyrrolidine-2 ',3 ''-indoline]-4 '-carboxylate
    Savithri, M. P.
    Suresh, M.
    Raghunathan, R.
    Raja, R.
    SubbiahPandi, A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O142 - +