Ethyl 1''-benzyl-1'-methyl-2''-oxodispiro[indeno[1,2-b]quinoxaline-11,3'pyrrolidine-2',3''-indoline]-4'-carboxylate

被引:1
|
作者
Kannan, Piskala Subburaman [1 ]
Lanka, Srinu [2 ]
Thennarasu, Sathiah [2 ]
Govindan, Elumalai [3 ]
SubbiahPandi, Arunachalathevar [3 ]
机构
[1] SMK Fomra Inst Technol, Dept Phys, Chennai 603103, Tamil Nadu, India
[2] CSIR, Cent Leather Res Inst, Organ Chem Div, Chennai 600020, Tamil Nadu, India
[3] Presidency Coll Autonomous, Dept Phys, Chennai 600005, Tamil Nadu, India
关键词
D O I
10.1107/S1600536813011525
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C36H30N4O3, the quinoxaline-indene system is roughly planar, with a maximum deviation from the mean plane of 0.218 angstrom for the C atom shared with the central pyrrolidine ring. This latter ring forms dihedral angles of 84.54 (7) and 83.91 (8)degrees with the quinoxaline-indene system and the indole ring, respectively. The central pyrrolidine ring has an envelope conformation with the N atom as the flap, while the pyrrolidine and five-membered rings of the indole group adopt twisted conformation and envelope (with the C atom bearing the quinoxaline-indene system as the flap) conformations, respectively. In the crystal, molecules are linked via weak C-H ... N hydrogen bonds, forming a chain running along [100].
引用
收藏
页码:O822 / +
页数:11
相关论文
共 50 条
  • [1] Crystal structure of methyl 3 '-benzamido-4 '-(4-methoxyphenyl)-1 '-methylspiro[indeno[1,2-b]quinoxaline-11,2 '-pyrrolidine]-3 '-carboxylate
    Chandralekha, Kuppan
    Sureshbabu, Adukamparai Rajukrishnan
    Gavaskar, Deivasigamani
    Lakshmi, Srinivasakannan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1257 - +
  • [2] 4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11 '-indeno[1,2-b]-quinoxaline]
    Vijayakumar, B.
    Sureshbabu, A. R.
    Gavaskar, D.
    Raghunathan, R.
    Velmurugan, D.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1576 - +
  • [3] Crystal structure of ethyl (2S,2 ' R)-1 '-benzyl-3-oxo-3H-dispiro[1-benzothiophene-2,3 '-pyrrolidine-2 ',11 ''-indeno[1,2-b]quinoxaline]-4 '-carboxylate
    Govindaraj, J.
    Raja, R.
    Suresh, M.
    Raghunathan, R.
    SubbiahPandi, A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O195 - +
  • [4] Regio- and stereoselective 1,3-dipolar cycloaddition of indenoquinoxalinone azomethine ylides to β-nitrostyrenes: synthesis of spiro[indeno[1,2-b]quinoxaline-11,3′-pyrrolizidines] and spiro[indeno[1,2-b]quinoxaline-11,2′-pyrrolidines]
    Barkov, Aleksey Yi.
    Zimnitskiy, Nikolay S.
    Korotaev, Vladislav Yu.
    Kutyashev, Igor B.
    Moshkin, Vladimir S.
    Sosnovskikh, Vyacheslav Ya.
    CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2017, 53 (04) : 451 - 459
  • [5] Regio- and stereoselective 1,3-dipolar cycloaddition of indenoquinoxalinone azomethine ylides to β-nitrostyrenes: synthesis of spiro[indeno[1,2-b]quinoxaline-11,3'-pyrrolizidines] and spiro[indeno[1,2-b]quinoxaline-11,2'-pyrrolidines]
    Aleksey Yi. Barkov
    Nikolay S. Zimnitskiy
    Vladislav Yu. Korotaev
    Igor B. Kutyashev
    Vladimir S. Moshkin
    Vyacheslav Ya. Sosnovskikh
    Chemistry of Heterocyclic Compounds, 2017, 53 : 451 - 459
  • [6] Ethyl 1 ''-benzyl-2 ''-oxo-2 ',3 ',5 ',6 ',7 ',7a '-hexahydro-1 ' H-dispiro[indeno[1,2-b]quinoxaline-11,2 '-pyrrolizine-3 ',3 '' indoline]-1 '-carboxylate monohydrate
    Kannan, Piskala Subburaman
    Lanka, Srinu
    Thennarasu, Sathiah
    Vimala, Gopal
    SubbiahPandi, Arunachalathevar
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O854 - +
  • [7] 1"-Benzyl-1′-methyl-4′-(naphthalen-1-yl)-naphthalene-2-spiro-3′-pyrrolidine-2′-spiro-3"-indoline-1,2"-dione
    Selvanayagam, S.
    Sridhar, B.
    Saravanan, P.
    Raghunathan, R.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1678 - U621
  • [8] 1 ',1 ''-Dimethyl-4 '-phenyldispiro[11H-indeno[1,2-b]quinoxaline-11,2 '-pyrrolidine-3 ',3 ''-piperidin]-4 ''-one
    Suresh, J.
    Nagalakshmi, R. A.
    Malathi, K.
    Kumar, R. R.
    Lakshman, P. L. N.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1433 - +
  • [9] Crystal structures of ethyl (2S*,2 ' R*)-1 '-methyl-2 '',3-dioxo-2,3-dihydrodispiro[1-benzothiophene-2,3 '-pyrrolidine-2 ',3 ''-indoline]-4 '-carboxylate and ethyl(2S*,2 ' R*)-5 ''-chloro-1 '-methyl-2 '',3-dioxo-2,3-di-hydrodispiro[1-benzothiophene-2,3 '-pyrrolidine-2 ',3 ''-indoline]-4 '-carboxylate
    Savithri, M. P.
    Suresh, M.
    Raghunathan, R.
    Vimala, G.
    Raja, R.
    SubbiahPandi, A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2014, 70 : 94 - +
  • [10] Synthesis of dispiro[indeno[1,2-b]quinoxaline-11,3′-pyrrolizine-2′,2"-[1,3]thiazolo[3,2-a]pyrimidine via cycloaddition reactions
    Ren, Demin
    Hu, Xiaolian
    Huang, Yulin
    Li, Xiaofang
    JOURNAL OF CHEMICAL RESEARCH, 2018, (09) : 453 - 455