ASYMMETRIC EPOXIDATION OF ALLYL ALCOHOL DERIVATIVES BY OMEGA-HYDROXYLASE FROM PSEUDOMONAS-OLEOVORANS

被引：0

作者：

FU, H

SHEN, GJ

WONG, CH

机构：

来源：

RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY | 1991年 / 110卷 / 05期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper described the application of non-heme monooxygenase system from Pseudomonas oleovorans to the syntheses of chiral 3-(benzyloxy)-, 3-(allyloxy)-, 3-(butyloxy)- and 3-(aryloxy)-1,2-epoxypropanes (6) from their corresponding allyl alcohol derivatives. The epoxides were determined to be R forms with good enantiomeric excess. The specificities of the enzymatic epoxidation of olefines and hydroxylation of the radical probe trans-2-phenyl-1-methylcyclopropane were discussed with regard to the reaction mechanism.

引用

页码：167 / 170

页数：4

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