Transfer hydrogenation of a carbonyl compound in glycerol-based solvent mixtures

被引：0
|
作者：
Wolfson, Adi [1 ]
Abu-Zaed, Hamdy [1 ]
Tavor, Dorith [1 ]
机构：
[1] Sami Shamoon Coll Engn, Green Proc Ctr, Bialik St 56, IL-84100 Beer Sheva, Israel
来源：
ORGANIC COMMUNICATIONS | 2016年 / 9卷 / 01期
关键词：
Glycerol; triacetin; green chemistry and sustainable solvent;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Three representative carbonyl compounds were efficiently hydrogenated in a glycerol-triacetin or glycerol-tributyrin mixture. The addition of triacetin to glycerol favorably altered the polarity of the reaction mixture, thereby increasing the solubility of reactants and, in turn, reactant conversion rates. Maximum conversion was detected in a glycerol-triacetin mixture (80:20) in the presence of a Ru(p-cymene)Cl-2-dimer catalyst.
引用
收藏
页码：9 / 14
页数：6
相关论文
共 50 条
  • [1] Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction
    Umi Syahirah Binti Mohd Amin
    Noridah B. Osman
    Yoshimitsu Uemura
    Nik Muhammad Nik Ab. Majid
    Waste and Biomass Valorization, 2020, 11 : 5591 - 5597
  • [2] Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction
    Amin, Umi Syahirah Binti
    Osman, Noridah B.
    Uemura, Yoshimitsu
    Majid, Nik Muhammad Nik Ab.
    WASTE AND BIOMASS VALORIZATION, 2020, 11 (10) : 5591 - 5597
  • [3] Hydroxyacetone: A Glycerol-Based Platform for Electrocatalytic Hydrogenation and Hydrodeoxygenation Processes
    Sauter, Waldemar
    Bergmann, Olaf L.
    Schroeder, Uwe
    CHEMSUSCHEM, 2017, 10 (15) : 3105 - 3110
  • [4] Design of Glycerol-Based Solvents for the Immobilization of Palladium Nanocatalysts: A Hydrogenation Study
    Leal-Duaso, Alejandro
    Favier, Isabelle
    Pla, Daniel
    Pires, Elisabet
    Gomez, Montserrat
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (19) : 6875 - 6885
  • [5] Opinions on glycerol-based deep eutectic solvent nanofluids for energy transportation
    Liu, Changhui
    Sun, Wenjie
    Liu, Qingyi
    FRONTIERS IN ENERGY RESEARCH, 2022, 10
  • [6] Regiospecific solvent-free transfer hydrogenation of α,β-unsaturated carbonyl compounds catalyzed by a cationic ruthenium(II) compound
    Naskar, Sipra
    Bhattacharjee, Manish
    TETRAHEDRON LETTERS, 2007, 48 (03) : 465 - 467
  • [7] Liquefaction behaviors of bamboo residues in a glycerol-based solvent using microwave energy
    Qi, J. (qijinqiu2005@aliyun.com), 1600, John Wiley and Sons Inc (131):
  • [8] Liquefaction Behaviors of Bamboo Residues in a Glycerol-Based Solvent Using Microwave Energy
    Xie, Jiulong
    Hse, Chung-Yun
    Shupe, Todd F.
    Qi, Jinqiu
    Pan, Hui
    JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (09)
  • [9] Iridium NHC Based Catalysts for Transfer Hydrogenation Processes Using Glycerol as Solvent and Hydrogen Donor
    Azua, Arturo
    Mata, Jose A.
    Peris, Eduardo
    ORGANOMETALLICS, 2011, 30 (20) : 5532 - 5536
  • [10] Glycerol as solvent and hydrogen donor in transfer hydrogenation-dehydrogenation reactions
    Wolfson, Adi
    Dlugy, Christina
    Shotland, Yoram
    Tavor, Dorith
    TETRAHEDRON LETTERS, 2009, 50 (43) : 5951 - 5953
12345