SYNTHESIS OF L-RIBONO-LACTONE AND L-LYXONO-LACTONE

被引：24

作者：

KOLD, H ^{[1
]}

LUNDT, I ^{[1
]}

PEDERSEN, C ^{[1
]}

机构：

[1] TECH UNIV DENMARK,DEPT ORGAN CHEM,DK-2800 LYNGBY,DENMARK

来源：

ACTA CHEMICA SCANDINAVICA | 1994年 / 48卷 / 08期

关键词：

D O I：

10.3891/acta.chem.scand.48-0675

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

L-Ribonolactone has been prepared in good yield by treatment of 2,3-O-isopropylidene-5-O-methanesulfonyl-D-lyxono-1,4-lactone with aqueous base. It was isolated as 3,4-O-benzylidene-L-ribono-1.5-lactone. A similar treatment of 2,3-O-isopropylidene-5-O-methanesulfonyl-D-ribono-1.4-lactone gave L-lyxonolactone, isolated as the 3,5-O-benzylidene derivative. The mechanisms of the reactions, as well as those of the reaction of 5-bromo-5-deoxy-D-ribono- and D-lyzono-1,4-lactone, with aqueous base have been studied.

引用

页码：675 / 678

页数：4

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