A SIMPLE ROUTE TO N-ACYLAMINOPHOSPHONOACETATES (N-PROTECTED PHOSPHONYLGLYCINE ESTERS)

被引:0
|
作者
FERRIS, L
HAIGH, D
MOODY, CJ
机构
[1] UNIV LOUGHBOROUGH,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND
[2] SMITHKLINE BEECHAM PHARMACEUT,EPSOM KT18 5XQ,SURREY,ENGLAND
关键词
DIAZOPHOSPHONATE; AMINOPHOSPHONATE; RHODIUM CARBENOID;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Rhodium(II) acetate catalysed reaction of triethyl diazophosphonoacetate 2 with amides, carbamates or ureas gives a range of N-acyl phosphonylglycine derivatives 3 by N-H insertion reaction of the intermediate rhodium carbenoid.
引用
收藏
页码:921 / &
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