SYNTHESIS AND COMPLEXATION CHEMISTRY OF THE NOVEL (1,3)-BIFUNCTIONAL ORGANOPHOSPHORUS(III) ESTERS [(RO)2PO]4SI (R = ME, ET)

被引：5
|
作者：
GREENE, N [1 ]
KEE, TP [1 ]
机构：
[1] UNIV LEEDS,SCH CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND
来源：
POLYHEDRON | 1993年 / 12卷 / 20期
关键词：
D O I：
10.1016/S0277-5387(00)83072-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new, silylated tetraphosphite compounds [(RO)2PO]4Si (R = Me, Et) have been synthesised in high yield from the reactions between SiCl4 and (RO)2P(=O)H in the presence of NEt3. These compounds can bridge two metal centres in the form of a bisbidentate, chelating ligand such as in the compounds {M}{[P(OMe)2O]2Si[O(OMe)2P]2} {M} {M = [Mo(CO)4] and [PtCl2]}.
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页码：2471 / 2475
页数：5
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