A NEW CLASS OF CHELATING DIPHOSPHITE - SYNTHESIS AND COMPLEXATION OF THE SILYLATED DIPHOSPHITES [(R1O)2PO]2SIR2R3 (R1 = ME, ET - R2, R3 = ME, PH, H,-CH=CH2)

被引：10

作者：

KEE, TP

PATEL, MT

机构：

[1] School of Chemistry, University of Leeds, Leeds

来源：

POLYHEDRON | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83271-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A general synthesis for a novel class of chelating diphosphites [(R1O)2PO]2 SiR2R3 (R2 = R3 = Me; R2 = R3 = Ph; R2 = Me, R3 = Ph; R2 = Me, R3 = H; R2 = Me, R3 = -CH = CH2; R1 = Me, Et) is reported. These diphosphite compounds react with MnBr(CO)5 giving the complexes fac-MnBr(CO)3{[R1O)2PO]2SiR2R3}.

引用

页码：135 / 137

页数：3

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[1] SYNTHESIS, CHARACTERIZATION AND REACTIVITY OF THE SILYLATED DIPHOSPHITES [(R1O)2PO]2SIR2R3 (R1 = ME, ET-R2, R3 = ME, PH, H, CH=CH2) - CRYSTAL-STRUCTURE OF [MNBR(CO)3(P(OME)2O)2SIME2]
SUM, V
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