CARBOHYDRATE PHOSPHINITES AS CHIRAL LIGANDS FOR ASYMMETRIC SYNTHESES CATALYZED BY COMPLEXES .11. INCREASE IN THE ENANTIOSELECTIVITY OF ASYMMETRIC HYDROGENATION IN WATER INFLUENCED BY SURFACTANTS OR POLYMERIZED MICELLES

被引：69

作者：

KUMAR, A

OEHME, G

ROQUE, JP

SCHWARZE, M

SELKE, R

机构：

[1] UNIV ROSTOCK,INST ORGAN KATALYSEFORSCH,ROSTOCK,GERMANY

[2] UNIV ROSTOCK,MAX PLANCK GESELL ARBEITSGRP ASYMMETR KATALYSE,D-18055 ROSTOCK,GERMANY

[3] UNIV MONTPELLIER 2,CHIM ORGAN PHYS LAB,MONTPELLIER,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 21期

关键词：

D O I：

10.1002/anie.199421971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Micelle‐forming substances or polymeric micelles 1 enhance not only the rate of the hydrogenation of esters of (Z)‐2‐N‐acyldehydroamino acids in water, but also its enantioselectivity. A high sensitivity of the optical induction to achiral modifiers is observed for the new precatalyst 2. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2197 / 2199

页数：3

共 49 条

[41] PHOSPHINITES OF CARBOHYDRATES AS CHIRAL LIGANDS FOR ASYMMETRIC SYNTHESIS CATALYZED BY COMPLEXES .1. HYDROGENATION OF AMINO-ACID PRECURSORS BY RHODIUM(I) CHELATES OF METHYL 4,6-O-BENZYLIDENE-2,3-BIS-O-(DIPHENYLPHOSPHINO)-ALPHA-D-GLUCOPYRANOSIDES
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REACTION KINETICS AND CATALYSIS LETTERS, 1979, 10 (02): : 135 - 138
[42] PHOSPHINITES OF CARBOHYDRATES AS CHIRAL LIGANDS FOR ASYMMETRIC-SYNTHESIS CATALYZED BY COMPLEXES .2. SUPERIORITY OF PHENYL 4,6-O-(R)-BENZYLIDENE-2,3-O-BIS(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE FOR RHODIUM(I)-CATALYZED HYDROGENATION OF AMINO-ACID PRECURSORS
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[43] Water soluble Ru (II)-p-cymene complexes of chiral aroylthiourea ligands derived from unprotected D/L-alanine as proficient catalysts for asymmetric transfer hydrogenation of ketones
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[44] PHOSPHINITES OF CARBOHYDRATES AS CHIRAL LIGANDS FOR ASYMMETRIC-SYNTHESIS CATALYZED BY COMPLEXES .3. IMMOBILIZATION OF CATIONIC RHODIUM(I) CHELATES OF PHENYL 4,6-O-(R)-BENZYLIDENE-2,3-O-BIS(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE ON CATION EXCHANGERS FOR HYDROGENATION OF DEHYDROAMINO ACIDS
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[45] Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by New Chiral C2-Symmetric Bis(sulfonyl) tetraaza Ligands Complexed with [Ru(η 6-p-cymene)Cl2]2 in Water
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[46] Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by New Chiral C2-Symmetric Bis(sulfonyl) tetraaza Ligands Complexed with [Ru(η6-p-cymene)Cl2]2 in Water
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[47] A comparison of the asymmetric hydrogenation catalyzed by rhodium complexes containing chiral ligands with a binaphthyl unit and those with a 5,5′,6,6′,7,7′,8,8′-octahydro-binaphthyl unit
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[48] STRUCTURAL REQUIREMENTS IN CHIRAL DIPHOSPHINE-RHODIUM COMPLEXES .11. ASYMMETRIC HOMOGENEOUS HYDROGENATION OF Z-ALPHA-ACYLAMINOCINNAMIC ACIDS AND ESTERS WITH (1S, 2S)-TRANS-1,2-BIS(DIPHENYLPHOSPHINOMETHYL) CYCLOHEXANE-RHODIUM(I) COMPLEXES
GLASER, R
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BLUMENFELD, J
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TETRAHEDRON, 1978, 34 (15) : 2405 - 2408
[49] Asymmetric Transfer Hydrogenation of Ketones in Aqueous Solution Catalyzed by Rhodium(III) Complexes with C2-Symmetric Fluorene-Ligands Containing Chiral (1R,2R)-Cyclohexane-1,2-diamine
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