1,3-DIPOLAR CYCLOADDITION REACTIONS OF 1,4-BENZOQUINONES WITH NITRILIMINES

被引：7
|
作者：
ARGYROPOULOS, NG [1 ]
MENTZAFOS, D [1 ]
TERZIS, A [1 ]
机构：
[1] DEMOCRITOS NATL RES CTR PHYS SCI,GR-15310 ATHENS,GREECE
来源：
JOURNAL OF HETEROCYCLIC CHEMISTRY | 1990年 / 27卷 / 07期
关键词：
D O I：
10.1002/jhet.5570270725
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The cycloaddition reactions of some aryl conjugated p-benzoquinones with nitrilimines were studied. Depending upon the reaction conditions mono- and/or bis- adducts were isolated only from carbon-carbon double bond. The structure determination was unequivocally established by an X-ray analysis carried out on a bis-adduct. The observed regio-, as well as site-selectivity, was qualitatively correlated with frontier molecular orbitals of the reacting species.
引用
收藏
页码：1983 / 1988
页数：6
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