PERTURBATION ANALYSIS OF CATALYTIC CURRENT AT A ROTATING-DISK ELECTRODE

被引：8
|
作者：
LIN, YP [1 ]
WU, H [1 ]
SELMAN, JR [1 ]
机构：
[1] IIT, DEPT CHEM ENGN, CHICAGO, IL 60616 USA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1990年 / 29卷 / 07期
关键词：
D O I：
10.1021/ie00103a017
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A perturbation method has been developed to analyze the kinetics of a catalytic reaction system where the product of a heterogeneous reaction reacts homogeneously to re-form the reactant. This is used to investigate the kinetics of Fenton's reagent using a platinum rotating disk electrode (RDE). The rate constants of the reaction were found to be 135 M-1s-1in the forward direction and 1.5 M-1s-1in the backward direction. © 1990, American Chemical Society. All rights reserved.
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页码：1189 / 1194
页数：6
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