SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DIETHYLAMINOGALLANE DIMER, [H2GAN(CH2CH3)2]2

被引：0
|
作者：
LORBERTH, J
DORN, R
MASSA, W
WOCADLO, S
机构：
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1993年 / 48卷 / 02期
关键词：
DIETHYLAMINE-GALLANE; DIETHYLAMIDO-GALLANE; SYNTHESIS; CRYSTAL STRUCTURE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound was prepared by reacting gallane etherate H3Ga.OEt2 at -40-degrees-C in Et2O with diethylamine upon warming to room temperature for several hours. It forms white crystals from ether solution which were identified by X-ray structure determination. Space group C2/c, Z = 4; 930 observed unique reflections, R/wR = 0.0482/0.0450. Lattice dimensions at 193 K: a = 1292.9(3), b = 721.1(2), c = 1443.1(2) pm; beta = 92.81(2)degrees. The structure reveals a centrosymmetric dimeric molecule with a planar square (GaN)2 fourmembered ring: average distance Ga-N 201.7 pm, Ga...Ga 284.5(2) pm.
引用
收藏
页码：224 / 226
页数：3
相关论文
共 50 条
  • [41] Synthesis, crystal structure, and luminescence of a new coordination polymer, {[Cd9(IDC)2(HIDC)6(Bipy)4] • 2N(CH3)(CH2CH3)2 • 2DMF}n
    Yang, Kun
    Wang, Zhuan-Zhuan
    Liu, Zhi-Hong
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (13) : 2286 - 2295
  • [42] SYNTHESIS AND CRYSTAL STRUCTURE OF MgCl2（CH3COOC2H5）2
    肖士镜
    钱民协
    竺迺珏
    唐有祺
    Science China Chemistry, 1987, (12) : 1247 - 1252
  • [43] SYNTHESIS AND THERMAL-DECOMPOSITION OF PALLADACYCLOPENTANE DERIVATIVES OF THE TYPE [PD(CH2CHRCHRCH2)L2] (R = H OR ME) - X-RAY CRYSTAL-STRUCTURE OF [PD(CH2CH2CH2CH2)(BIPY)]
    DIVERSI, P
    INGROSSO, G
    LUCHERINI, A
    LUMINI, T
    MARCHETTI, F
    ADOVASIO, V
    NARDELLI, M
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (01): : 133 - 140
  • [44] CRYSTAL MOLECULAR-STRUCTURE OF N-METHYLDIETHANOLAMINOGALLANE DIMER, [CH3N(CH2CH2O)2GAH]2
    RETTIG, SJ
    STORR, A
    TROTTER, J
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1974, 52 (12): : 2206 - 2215
  • [45] SYNTHESIS AND CRYSTAL-STRUCTURE OF K4[CU(CH3COO)4](CH3COO)2-CENTER-DOT-2CH3COOH-CENTER-DOT-2H2O
    SABIROV, VK
    PORAIKOSHITS, MA
    STRUCHKOV, YT
    KOORDINATSIONNAYA KHIMIYA, 1994, 20 (8-9): : 691 - 696
  • [46] Synthesis and spectral studies of diorganotin heterocyclic dithiocarbamate complexes: The crystal structure of (CH3)(2)Sn[S2CNCH2 CH2CH(2)CH(2)CH(2)](2)
    Sharma, J
    Singh, Y
    Bohra, R
    Rai, AK
    POLYHEDRON, 1996, 15 (07) : 1097 - 1102
  • [47] Conformational characteristics and unperturbed chain dimensions of the oxygen-containing polymers [-OCH(2)CR(2)CH(2)-](n) with R=H, CH3, and CH2CH3
    Welsh, WJ
    Abbassi, Q
    Galiatsatos, V
    Taylor, GK
    MACROMOLECULES, 1996, 29 (03) : 993 - 999
  • [48] Synthesis and crystal structure of [(NH2CH2CH2NH3)2WVIO2(NHC6H4NH)2]2(NH2CH2CH2NH2)•H2O
    Lu, XM
    Song, FG
    Wang, B
    Li, L
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (05) : 753 - 756
  • [49] (CH3NH2CH3)[REBR6] CRYSTAL-STRUCTURE
    SERGIENKO, VS
    PORAIKOSHITS, MA
    KOTEGOV, KV
    KOORDINATSIONNAYA KHIMIYA, 1984, 10 (08): : 1140 - 1141
  • [50] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A DIALKYLDICYCLOPENTADIENYLYTTRIUM COMPLEX - [(C5H5)2Y[CH2SI(CH3)3]2]2LI2(CH3OCH2CH2OCH3)2(C4H8O2)
    EVANS, WJ
    DOMINGUEZ, R
    LEVAN, KR
    DOEDENS, RJ
    ORGANOMETALLICS, 1985, 4 (10) : 1836 - 1841
12345