The initial adsorption stages and the interaction of oxygen on FeSi surfaces have been studied as a function of exposure and annealing temperature using a variety of techniques including HREELS, AES, LEED, XPS and UPS. O2 was found to adsorb dissociatively on the FeSi surfaces at room temperature. The whole adsorption process can be divided into four stages. Heating promotes the oxidation of Si, and a thin SiO2 overlayer is formed on the surface when annealed at 450-degrees-C, while all FeOx species are reduced. Models for adsorbed atomic O on the FeSi(100) surface exposed to different oxygen exposures have been put forward to account for the observed experimental results.
机构:
Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Shaanxi, Peoples R China
Chinese Univ Hong Kong, Dept Phys, Shatin, Hong Kong, Peoples R ChinaNorthwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Shaanxi, Peoples R China
Fan, X. L.
Lau, W. M.
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Chinese Univ Hong Kong, Dept Phys, Shatin, Hong Kong, Peoples R China
Univ Western Ontario, London, ON N6A 5B7, CanadaNorthwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Shaanxi, Peoples R China
Lau, W. M.
Liu, Z. F.
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Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
Chinese Univ Hong Kong, Ctr Sci Modeling & Computat, Shatin, Hong Kong, Peoples R ChinaNorthwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Shaanxi, Peoples R China
机构:
Advanced Key Technologies Division, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba-shi, Ibaraki,305-0047, JapanAdvanced Key Technologies Division, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba-shi, Ibaraki,305-0047, Japan
Kurahashi, Mitsunori
Yamauchi, Yasushi
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Advanced Key Technologies Division, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba-shi, Ibaraki,305-0047, JapanAdvanced Key Technologies Division, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba-shi, Ibaraki,305-0047, Japan