PHOTOSUBSTITUTION OF FE(CO)5 WITH PET3 IN CYCLOHEXANE - FE(CO)4PET3 AND FE(CO)3(PET3)2 AS SINGLE-PHOTON PRODUCTS

被引：16

作者：

NAYAK, SK ^{[1
]}

BURKEY, TJ ^{[1
]}

机构：

[1] MEMPHIS STATE UNIV,DEPT CHEM,MEMPHIS,TN 38152

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 07期

关键词：

D O I：

10.1021/ic00033a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Substitution of two ligands on a metal carbonyl complex upon the absorption of a single photon is well-known in the gas phase but not in solution. A single-photon absorption by Fe(CO)5 leads to the formation of Fe(CO)3(PEt3)2 as the major product in cyclohexane in the presence of PEt3. Our results are consistent with Fe(CO)3(PEt3)2 being formed via a triplet monosubstituted product. The triplet could then dissociate CO to form Fe(CO)3(PEt3)2 [GRAPHICS]

引用

页码：1125 / 1127

页数：3

共 50 条

[21] Synthesis and reactivity of (η3-pentadienyl)Ir(PEt3)2 and (η3-2,4-dimethylpentadienyl)Ir(PEt3)2
Organometallics, 4 (1667):
[22] Rational synthesis of high nuclearity Mo/Fe/S clusters:: The reductive coupling approach in the convenient synthesis of (Cl4-cat)2Mo2Fe6S8(PR3)6 [R = Et, nPr, nBu] and the new [(Cl4-cat)2Mo2Fe2S3O(PEt3)3Cl]•1/2(Fe(PEt3)2(MeCN)4) and (Cl4-cat)2Mo2Fe3S5(PEt3)5 clusters
Han, J
Koutmos, M
Al Ahmad, S
Coucouvanis, D
INORGANIC CHEMISTRY, 2001, 40 (23) : 5985 - 5999
[23] Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6+ (M = Mn, Fe, Co, Ni) nanoclusters
Gholipour-Ranjbar, Habib
Deepika
Jena, Puru
Laskin, Julia
COMMUNICATIONS CHEMISTRY, 2022, 5 (01)
[24] Gas-phase fragmentation of single heteroatom-incorporated Co5MS8(PEt3)6+ (M = Mn, Fe, Co, Ni) nanoclusters
Habib Gholipour-Ranjbar
Puru Deepika
Julia Jena
Communications Chemistry, 5
[25] Synthesis and characterization of Ir(H)(CO)(PEt3)2(η2-C60)
Ee, Chang Yeon L.
Lee, Gaehang
Kang, Hongkyu
Park, Bo Kenn
Park, Joon T.
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2007, 28 (11) : 1958 - 1962
[26] PHOSPHORUS DONOR LIGAND SUBSTITUTION IN PENTANUCLEAR OSMIUM CLUSTER CARBONYLS - CRYSTAL AND MOLECULAR-STRUCTURES OF [OS5H2(CO)14(PET3)] AND [OS5H2(CO)13(PET3)P(OME)3]
JOHNSON, BFG
LEWIS, J
RAITHBY, PR
ROSALES, MJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 259 (02) : C9 - C14
[27] [{Fe(PEt3)3}2(μ-H)6B][BPh4]:: A complex containing octahedral hypercoordinate boron
Hillier, AC
Jacobsen, H
Gusev, D
Schmalle, HW
Berke, H
INORGANIC CHEMISTRY, 2001, 40 (24) : 6334 - +
[28] APPLICATION OF THE CONCERTED BRIDGE OPENING CLOSING MECHANISM TO THE FLUXIONALITY OF [FE3(CO)10(L)(CNCF3)] (L = CO, PME3, PET3, P(OME)3, P(OET)3)
MANN, BE
ORGANOMETALLICS, 1992, 11 (01) : 481 - 482
[29] ENANTIOSELECTIVE BENZYLIDENE TRANSFER-REACTIONS USING THE CHIRAL-AT-IRON BENZYLIDENE COMPLEXES (SFESC)-CP(CO)(PH2(S)-2-METHYLBUTYLP)FE=CHC6H5+ AND (RFESC)-CP(CO)(PH2(S)-2-METHYLBUTYLP)FE=CHC6H5+ AND (SFE)-CP(CO)(PET3)FE=CHC6H5+ AND (RFE)-CP(CO)(PET3)FE=CHC6H5+
BROOKHART, M
BUCK, RC
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) : 111 - 127
[30] STUDIES OF THE DYNAMIC EQUILIBRIUM INVOLVING W2CL6(PET3)4 AND W2CL6(PET3)3 AND PREPARATION, STRUCTURE AND BONDING IN [ET3PH]+[W4O3CL7(PET3)3]
BARRY, JT
CHACON, ST
FOLTING, K
CHISHOLM, MH
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 99 - INOR

← 1 2 3 4 5 →