F-19 SOLVENT SHIFTS AS MOLECULAR ENVIRONMENTAL PROBES

被引：7
|
作者：
SUNTIOINEN, S
LAATIKAINEN, R
机构：
[1] Department of Chemistry, University of Kuopio, Kuopio, SF-70211
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 1991年 / 29卷 / 05期
关键词：
FLUORINE NMR; SOLVENT EFFECTS; CHEMICAL SHIFTS; CHEMOMETRICS;
D O I：
10.1002/mrc.1260290505
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The F-19 solvent shifts of trichlorofluoromethane, fluorobenzene and methyl trifluoracetate were measured with respect to an external reference in 48 solvents and solvent mixtures. The data were modelled using various linear and thermodynamic approaches. The models based only on the chemical composition of the solvent explain the results with a correlation coefficient of 0.95-0.96, corresponding to an r.m.s. value of 0.14-0.21 ppm. Including the refractivities improves the fit slightly in some cases.
引用
收藏
页码：433 / 439
页数：7
相关论文
共 50 条
  • [31] POLAR FIELD EFFECTS ON F-19 CHEMICAL-SHIFTS - IMPORTANT EFFECT
    ADCOCK, W
    GUPTA, BD
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (23) : 6871 - 6873
  • [32] F-19 NMR CHEMICAL-SHIFTS AND THE MICROSTRUCTURES OF FLUORINE CONTAINING POLYMERS
    TONELLI, AE
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1980, 25 (03): : 399 - 399
  • [33] PRIORI CALCULATIONS OF H-1 AND F-19 CHEMICAL-SHIFTS
    STAHLLARIVIERE, H
    ORGANIC MAGNETIC RESONANCE, 1974, 6 (03): : 170 - 177
  • [34] F-19 NMR CHEMICAL-SHIFTS OF PHOTOCOMPLEXES AND DONOR PROPERTIES OF LIGANDS
    IGNATOV, ME
    ILIIN, EG
    SHVETS, AA
    BUSLAEV, IA
    DOKLADY AKADEMII NAUK SSSR, 1978, 240 (04): : 865 - 868
  • [35] F-19 MR SOLVATE ISOTOPE SHIFTS OF THE FLUORIDE-ION IN ALCOHOLS
    SHCHERBAKOV, VA
    MIKHALEV, VA
    JOURNAL OF STRUCTURAL CHEMISTRY, 1982, 23 (05) : 797 - 799
  • [36] ABSOLUTE MAGNETIC ANALYSIS OF F-19(P,P')F-19 REACTION
    GOSSETT, CR
    PHILLIPS, GC
    EISINGER, JT
    PHYSICAL REVIEW, 1955, 98 (03): : 724 - 727
  • [37] NOVEL FLUORINATED POLYMERIC MOLECULAR PROBES FOR F-19 MAGNETIC-RESONANCE-IMAGING - SYNTHESES AND CHARACTERIZATION OF FLUORINATED BIOPOLYMERS
    MEHTA, VD
    KULKARNI, PV
    MASON, RP
    BABCOCK, EE
    CONSTANTINESCU, A
    ANTICH, PP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 41 - MEDI
  • [38] C-13-F-19 COUPLINGS AND F-19 NMR SHIFTS OF CYCLOALKYL, BICYCLOALKYL AND STEROID MONOFLUORO COMPOUNDS
    SCHNEIDER, HJ
    GSCHWENDTNER, W
    HEISKE, D
    HOPPEN, V
    THOMAS, F
    TETRAHEDRON, 1977, 33 (14) : 1769 - 1773
  • [39] F-19 NMR-SPECTROSCOPY IN MONITORING FLUORINATED-SOLVENT REGENERATION
    OGORODNIKOV, VD
    BORDUNOV, VV
    INDUSTRIAL LABORATORY, 1986, 52 (09): : 820 - 821
  • [40] C-13 AND F-19 CHEMICAL-SHIFTS OF BRIDGEHEAD HALOGENATED ADAMANTANES
    PERKINS, RR
    PINCOCK, RE
    ORGANIC MAGNETIC RESONANCE, 1976, 8 (03): : 165 - 169
12345