ZIRCONA[1]METALLOCYCLOPHANES - SYNTHESIS, PROPERTIES, AND STRUCTURE OF (TBU-ETA(5)-C5H4)(2)ZR(ETA(1)-1,ETA(1)-1')(ETA(6)-C6H5)(2)V AND ITS CHROMIUM ANALOG

被引：35

作者：

ELSCHENBROICH, C

SCHMIDT, E

METZ, B

HARMS, K

机构：

[1] Fachbereich Chemie der Philipps-Universität

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 09期

关键词：

D O I：

10.1021/om00009a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tilt caused by the one-atom interannular bridge in a zirconocene unit in 7 imposed at bis(eta(6)-benzene)vanadium (3(.)) is very small. As judged from EPR spectroscopy, the electronic structure of 3(.) is virtually unaffected by zircona[1]vanadocyclophane formation. The novel binuclear complexes are very robust thermally but quite labile chemically. The latter property precludes a thorough electrochemical study of metal-metal interaction in 7(.).

引用

页码：4043 / 4045

页数：3

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