(2,3,7,8,12,13,17,18-OCTAETHYLPORPHINATO)PERCHLORATOMANGANESE(III)

被引：6

作者：

CHENG, BS

SCHEIDT, WR

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194013181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of [Mn(OEP)(OClO3)] (where OEP = C36H44N4) has been determined. The axial Mn-O bond length is 2.183 (2) Angstrom and the equatorial Mn-N-p bond lengths have an average value of 2.000 (5) Angstrom. The molecules form weak dimers in the solid state with interring distances of 3.49 Angstrom and a lateral shift of 3.27 Angstrom. The compound is found to be isomorphous with the iron derivative [Fe(OEP)(OClO3)]. A brief comparison of the structural parameters for the two molecules is given.

引用

页码：825 / 828

页数：4

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