(2,3,7,8,12,13,17,18-OCTAETHYLPORPHINATO)PERCHLORATOMANGANESE(III)

被引：6
|
作者：
CHENG, BS
SCHEIDT, WR
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷
关键词：
D O I：
10.1107/S0108270194013181
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of [Mn(OEP)(OClO3)] (where OEP = C36H44N4) has been determined. The axial Mn-O bond length is 2.183 (2) Angstrom and the equatorial Mn-N-p bond lengths have an average value of 2.000 (5) Angstrom. The molecules form weak dimers in the solid state with interring distances of 3.49 Angstrom and a lateral shift of 3.27 Angstrom. The compound is found to be isomorphous with the iron derivative [Fe(OEP)(OClO3)]. A brief comparison of the structural parameters for the two molecules is given.
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页码：825 / 828
页数：4
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