DIRECT FLUORINATION OF NITROGEN-CONTAINING LADDER POLYMERS, 2 NEW GRAPHITIC FLUOROCARBON POLYMERS

被引:3
|
作者
KAMPA, JJ [1 ]
LAGOW, RJ [1 ]
机构
[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712
关键词
D O I
10.1021/cm00028a005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Paracyanogen and pyrolyzed poly(acrylonitrile) have been perfluorinated using elemental fluorine and have retained their polymeric fused ring structures. The two new materials produced by this method were characterized by infrared spectroscopy, electron impact mass spectrometry, elemental analysis, iodometric titration, and thermogravimetric analysis. Some chemical and physical properties are discussed as well as several possible applications in light of the discussed properties of these materials.
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页码:427 / 429
页数:3
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