INTRAMOLECULAR BASE COORDINATION ACCORDING TO NEED - 1-(DIMETHYLAMINOETHYL)-2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN THE COMPLEXES WITH S-BLOCK, P-BLOCK, D-BLOCK AND F-BLOCK ELEMENTS

被引：78

作者：

JUTZI, P

DAHLHAUS, J

KRISTEN, MO

机构：

[1] Fakultät für Chemie der Universität Bielefeld Universitätsstraße

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 450卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80167-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of cyclopentadienyl complexes containing the polydentate C5Me4(CH2CH2NMe2) ligand is described. The compounds (C5Me4CH2CH2NMe2)2M (M = Ca, Sm), (C5Me4CH2CH2 NMe2)AlEt2, [(C5Me4CH2CH2NMe2)M(CO)2]2 (M = Mo, Fe) and [(C5Me4CH2CH2NMe2)Fe(CO)2]+BF4- are obtained by standard procedures. Except for the dimeric metal carbonyls, all cyclopentadienyl compounds are characterized by an additional intramolecular coordination of the nitrogen atom in the side chain.

引用

页码：C1 / C3

页数：3