INTRAMOLECULAR BASE COORDINATION ACCORDING TO NEED - 1-(DIMETHYLAMINOETHYL)-2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN THE COMPLEXES WITH S-BLOCK, P-BLOCK, D-BLOCK AND F-BLOCK ELEMENTS

被引：78
|
作者：
JUTZI, P
DAHLHAUS, J
KRISTEN, MO
机构：
[1] Fakultät für Chemie der Universität Bielefeld Universitätsstraße
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 450卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)80167-A
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of cyclopentadienyl complexes containing the polydentate C5Me4(CH2CH2NMe2) ligand is described. The compounds (C5Me4CH2CH2NMe2)2M (M = Ca, Sm), (C5Me4CH2CH2 NMe2)AlEt2, [(C5Me4CH2CH2NMe2)M(CO)2]2 (M = Mo, Fe) and [(C5Me4CH2CH2NMe2)Fe(CO)2]+BF4- are obtained by standard procedures. Except for the dimeric metal carbonyls, all cyclopentadienyl compounds are characterized by an additional intramolecular coordination of the nitrogen atom in the side chain.
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页码：C1 / C3
页数：3
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