PHOSPHORYLATED RESORCINOL-BASED CYCLOPHANES

被引:0
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作者
MARKOVSKY, LN
KALCHENKO, VI
RUDKEVICH, DM
SHIVANYUK, AN
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O6 [化学];
学科分类号
0703 ;
摘要
Complete and partial O-functionalization of the octahydroxytetramethyl[1(4)]metacyclophane with phosphoryl groups has been carried out, and reversible intramolecular addition of hydroxy or trimethylsilyloxy groups to the neighbouring P=O bonds with the formation of spirophosphorane fragments has been shown to be typical of the 3,10,17,24-tetrahydroxy(tetrakistrimethylsiloxy)-5,12,19,26-tetrakis-o-phenylenephosphoryloxy-1,8,15,22-tetramethyl [1(4)]metacyclophane.
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页码:106 / 108
页数:3
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