INDIVIDUAL IONIC ACTIVITY-COEFFICIENTS FROM A SYMMETRICAL POISSON-BOLTZMANN THEORY

被引：43
|
作者：
MOLERO, M
OUTHWAITE, CW
BHUIYAN, LB
机构：
[1] UNIV SHEFFIELD,DEPT APPL & COMP MATH,SHEFFIELD S10 2TN,S YORKSHIRE,ENGLAND
[2] UNIV PUERTO RICO,DEPT PHYS,RIO PIEDRAS,PR 00931
来源：
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1992年 / 88卷 / 11期
关键词：
D O I：
10.1039/ft9928801541
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A symmetric Poisson-Boltzmann equation is used to calculate individual activity coefficients for 1 : 1 and 2 : 1 primitive model electrolytes. Comparisons are made with the mean-spherical approximation and hypernetted chain integral equation predictions and available Monte Carlo simulation results. A brief comparison is also made with the mean-spherical approximation and Monte Carlo results for the aqueous mixture KCI-KF.
引用
收藏
页码：1541 / 1547
页数：7
相关论文
共 50 条
  • [31] Poisson-Boltzmann theory with non-linear ion correlations
    Su, Mao
    Xu, Zhijie
    Wang, Yanting
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2019, 31 (35)
  • [32] Modified Poisson-Boltzmann equations and macroscopic forces in inhomogeneous ionic fluids
    Budkov, Yury A.
    Kolesnikov, Andrei L.
    JOURNAL OF STATISTICAL MECHANICS-THEORY AND EXPERIMENT, 2022, 2022 (05):
  • [33] MODIFIED POISSON-BOLTZMANN THEORY APPLIED TO LINEAR POLYELECTROLYTE SOLUTIONS
    DAS, T
    BRATKO, D
    BHUIYAN, LB
    OUTHWAITE, CW
    JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (01): : 410 - 418
  • [34] Poisson-Boltzmann theory for two parallel uniformly charged plates
    Xing, Xiangjun
    PHYSICAL REVIEW E, 2011, 83 (04):
  • [35] Incorporation of excluded-volume correlations into Poisson-Boltzmann theory
    Antypov, D
    Barbosa, MC
    Holm, C
    PHYSICAL REVIEW E, 2005, 71 (06):
  • [36] DISTRIBUTION OF IONS AROUND DNA - POISSON-BOLTZMANN THEORY AND EXPERIMENT
    LAMM, G
    SZABO, A
    BIOPHYSICAL JOURNAL, 1988, 53 (02) : A43 - A43
  • [37] Non-linear Poisson-Boltzmann theory for swollen clays
    De Carvalho, RJFL
    Trizac, E
    Hansen, JP
    EUROPHYSICS LETTERS, 1998, 43 (04): : 369 - 375
  • [38] A fluctuation-corrected functional of convex Poisson-Boltzmann theory
    Blossey, R.
    Maggs, A. C.
    JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL, 2018, 51 (38)
  • [39] ON THE SOLUTION OF THE POISSON-BOLTZMANN EQUATION WITH APPLICATION TO THE THEORY OF THERMAL EXPLOSIONS
    CHAMBRE, PL
    JOURNAL OF CHEMICAL PHYSICS, 1952, 20 (11): : 1795 - 1797
  • [40] STRUCTURE AND THERMODYNAMICS OF MICELLAR SOLUTIONS IN THE MODIFIED POISSON-BOLTZMANN THEORY
    BHUIYAN, LB
    OUTHWAITE, CW
    BRATKO, D
    CHEMICAL PHYSICS LETTERS, 1992, 193 (04) : 203 - 210
12345