Stanley Wawzonek and the Introduction of Polar Aprotic Solvents into Organic Electrochemistry

被引：1
|
作者：
Fry, Albert J. [1 ]
机构：
[1] Univ Wisconsin, Organ Chem, Madison, WI 53706 USA
来源：
ELECTROCHEMICAL SOCIETY INTERFACE | 2010年 / 19卷 / 01期
关键词：
D O I：
10.1149/2.F09101if
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Stilbene, anthracene, and 9-anisylidenefluorene are reduced stepwise polarographically in anhydrous acetonitrile and in dimethylformamide. Triphenylethylene, tetraphenylethylene, styrene, and 1,1-diphenylethylene give only one reduction wave. Large-scale electrolytic reductions in these solvents indicate that carbanion intermediates exist for a short period of time. 1,2,3,4-Tetraphenylbutane and meso-diphenyl succinic acid have been prepared electrolytically from stilbene in dimethylformamide.
引用
收藏
页码：55 / 58
页数：4
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