(2,5-NORBORNADIENE)RHODIUM(I) COMPLEXES WITH BIS(AZOL-1-YL)METHANE AND TRIS (AZOL-1-YL)METHANE

被引：19
|
作者：
BALLESTEROS, P
LOPEZ, C
LOPEZ, C
CLARAMUNT, RM
JIMENEZ, JA
CANO, M
HERAS, JV
PINILLA, E
MONGE, A
机构：
[1] UNIV COMPLUTENSE, FAC CIENCIAS QUIM, DEPT QUIM INORGAN 1, E-28040 MADRID, SPAIN
[2] UNIV COMPLUTENSE, FAC QUIM,CSIC,INST CIENCIAS MAT SEDE D, DIFRACC RAYOS X LAB, E-28040 MADRID, SPAIN
来源：
ORGANOMETALLICS | 1994年 / 13卷 / 01期
关键词：
D O I：
10.1021/om00013a042
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]bis(mu-chloro)dirhodium, [RhCl-(NBD)]2, with bis- and tris(azolyl)methanes have been performed in methanol and acetone with 1:1 and 1:2 [RhCl(NBD)]2/ligand molar ratios. The structures of the complexes have been characterized by infrared and H-1 and C-13 NMR spectroscopy as well as X-ray diffraction analysis. Cationic species have been evidenced in the solid state while equilibria between cationic and neutral species have been established in solution.
引用
收藏
页码：289 / 297
页数：9
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