[4+2]-CYCLOADDITION AND [2+4]-CYCLOADDITION PROCESSES OF 4,5-DICYANOPYRIDAZINE WITH 2,3-DIMETHYLBUTA-1,3-DIENE

被引:13
|
作者
NESI, R [1 ]
GIOMI, D [1 ]
TURCHI, S [1 ]
PAOLI, P [1 ]
机构
[1] UNIV FLORENCE,DIPARTIMENTO ENERGET,I-50139 FLORENCE,ITALY
关键词
D O I
10.1016/S0040-4020(01)85385-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title compounds afforded under relatively mild conditions the polycyclic systems 3a, 4, and 5 through alternative concomitant cycloadditions; the reactivity of the dicyanopyridazine system was critically influenced by the presence of methyl groups at the 3 and 6 positions. The skeleton of 3a and the stereochemistry of 5 were established by X-ray experiments.
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收藏
页码:9189 / 9194
页数:6
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