STRUCTURE OF DI(ETA-BUTYL)BIS(N,N-DIETHYLDITHIOCARBAMATO)TIN(IV) AT 153 K

被引：15
|
作者：
VRABEL, V [1 ]
LOKAJ, J [1 ]
KELLO, E [1 ]
GARAJ, J [1 ]
BATSANOV, AC [1 ]
STRUCHKOV, YT [1 ]
机构：
[1] AN NESMEYANOV ORGANOELEMENT CPDS INST, MOSCOW 117813, USSR
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1992年 / 48卷
关键词：
D O I：
10.1107/S0108270191010454
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Sn(C4H9)2(C5H10NS2)2], M(r) = 529.5, monoclinic, Pc, a = 12.434 (2), b = 11.913 (3), c = 18.822 (4) angstrom, beta = 115.31 (1)-degrees, V = 2520.4 (9) angstrom 3, Z = 4, D(m) = 1.39, D(x) = 1.40 Mg m-3, lambda(Mo K-alpha) = 0.71069 angstrom, mu = 1.34 mm-1, F(000) = 1096, low temperature (153 K), final R = 0.021 for 4225 unique observed reflections. The structures of the two crystallographically independent molecules show only minor differences. The N,N-diethyldithiocarbamate (dtc) ligands in both molecules are chelated to tin in an unsymmetrical fashion, with one longer (2.90-3.05 angstrom) and one shorter (2.50-2.55 angstrom) Sn-S bond. The Sn atom has a distorted octahedral environment.
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收藏
页码：633 / 635
页数：3
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