EFFECTS OF ANHARMONICITY ON INTRAMOLECULAR ELECTRON-TRANSFER RATES

被引：16
|
作者：
ISLAMPOUR, R
LIN, SH
机构：
[1] TEACHER TRAINING UNIV,DEPT CHEM,TEHRAN,IRAN
[2] CTR STUDY EARLY EVENTS PHOTOSYNTH,TEMPE,AZ 85287
来源：
CHEMICAL PHYSICS LETTERS | 1991年 / 179卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(91)90306-T
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A quantum mechanical expression for the electron transfer (ET) rate constant is derived using the cumulant expansion method. The effect of anharmonicity on ET rates is examined on the assumption that the anharmonic motion can be described by the Morse potential.
引用
收藏
页码：147 / 151
页数：5
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