KINETICS OF SYNTHESIS OF AMYL-TERT-BUTYL ETHER IN THE PRESENCE OF KU-23 SULFO CATION-EXCHANGER

被引：0
|
作者：
BARKOV, VI
ROZHNOV, AM
SHARONOV, KG
KOROLKOV, AV
机构：
来源：
KINETICS AND CATALYSIS | 1991年 / 32卷 / 02期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of liquid-phase synthesis of amyl-tert-butyl ether from n-amyl alcohol and isobutylene were investigated at 293-333 K in the presence of KU-23 sulfo cation-exchanger. The experimental results were processed with equations for homogeneous and heterogeneous catalysis. It was shown that the equation for homogeneous catalysis including a coefficient which considers the deviation from ideality calculated with the UNIFAC method gives the best description of the experimental data.
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页码：330 / 333
页数：4
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