Di-mu-methanolato-kappa O-4:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-kappa N-2)-(nitrato-kappa O)copper(II)

被引：1
|
作者：
Li, Xu-Guang [1 ]
Gao, Meng-Meng [2 ]
Ng, Seik Weng [3 ,4 ]
机构：
[1] Tibet Univ Nationalities, Med Sch, Fundamental Lab Life Sci, Xianyang 712082, Peoples R China
[2] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[4] King Abdulaziz Univ, Chem Dept, Jeddah, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S160053681201241X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Copper nitrate in methanol solution cleaves the N-C-methanol bond when reacted with 3-methyl-5-phenylpyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu-2(CH3O)(2)(NO3)(2)(C10H10N2)(4)], in which the Cu-II atom is linked to a nitrate ion, two methanolate ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate anion occupies the apical site. The crystal structure features intramolecular N-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M503 / +
页数：8
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