Di-mu-methanolato-kappa O-4:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-kappa N-2)-(nitrato-kappa O)copper(II)

被引：1
|
作者：
Li, Xu-Guang [1 ]
Gao, Meng-Meng [2 ]
Ng, Seik Weng [3 ,4 ]
机构：
[1] Tibet Univ Nationalities, Med Sch, Fundamental Lab Life Sci, Xianyang 712082, Peoples R China
[2] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[4] King Abdulaziz Univ, Chem Dept, Jeddah, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S160053681201241X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Copper nitrate in methanol solution cleaves the N-C-methanol bond when reacted with 3-methyl-5-phenylpyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu-2(CH3O)(2)(NO3)(2)(C10H10N2)(4)], in which the Cu-II atom is linked to a nitrate ion, two methanolate ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate anion occupies the apical site. The crystal structure features intramolecular N-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M503 / +
页数：8
相关论文
共 50 条
  • [1] Di-mu-hydroxido-kappa O-4:O-di-mu-perchlorato-kappa O-4:O '-bis[(2,2 '-bipyridine-kappa N-2,N ')-copper(II)]
    Saravanan, B.
    Jayamani, A.
    Sengottuvelan, N.
    Chakkaravarthi, G.
    Manivannan, V.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M600 - +
  • [2] Bis(2-aminomethyl-1H-benzimidazole-kappa N-2(2), N-3) bis(nitrato-kappa O) copper(II)
    Zhao, Jing
    Zhang, Heng
    Zhai, Xueliang
    Zhu, Guoyi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M767 - +
  • [3] Di-mu-benzoato-kappa O-3, O':O;kappa O-3:O,O'-bis-[aqua(nitrato-kappa O) (1,10-phenanthroline-kappa N-2,N')lead(II)]
    Cheng, Yuanzheng
    Yan, Fang
    Shi, Weiwei
    Zhang, Liping
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M528 - +
  • [4] Di-mu-acetato-kappa O-4:O-bis({N'-[(E)-phenyl-(pyridin-2-yl-kappa N)methylidene]benzo-hydrazidato-kappa N-2',O}copper(II))
    Vineetha, M. C.
    Sithambaresan, M.
    Jacob, Jinsa Mary
    Kurup, M. R. Prathapachandra
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1086 - +
  • [5] Bis(2, S-dimethyldithiocarbazate-kappa N-2(3),S)( nitrato-kappa O) copper(II) nitrate
    Hazari, Saroj K. S.
    Dey, B. K.
    Ganguly, B.
    Ng, Seik Weng
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M779 - +
  • [6] trans-Bis(nitrato-kappa O)bis(1,10-phenanthroline-kappa N-2,N ')manganese(II)
    Saphu, Watcharin
    Chanthee, Songwuit
    Chainok, Kittipong
    Harding, David J.
    Pakawatchai, Chaveng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1026 - +
  • [7] Di-mu-acetato-kappa O-4:O'-bis[(1,10-phenanthroline-kappa(2) N, N ')(trifluoromethanesulfonato-kappa O)copper(II)]
    Wannarit, Nanthawat
    Pakawatchai, Chaveng
    Youngme, Sujittra
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M591 - +
  • [8] [Aquabis(nitrato-kappa O)copper(II)]-mu-{bis[5methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua(nitrato-kappa O)copper(II)]nitratemonohydrate
    Seredyuk, Maksym
    Pavlenko, Vadim A.
    Gumienna-Kontecka, Elzbieta
    Iskenderov, Turganbay S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1472 - +
  • [9] (Nitrato-kappa O-2,O')bis(1,1'-phenanthroline-kappa(2) N, N') copper(II) tricyanomethanide
    Lackova, Katarina
    Potocnak, Ivan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1553 - +
  • [10] Diaquabis(nitrato-kappa O)bis(pyridine-kappa N)manganese(II)
    Alam, Naveed
    Shahid, Muhammad
    Rauf, M. Khawar
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M9 - +
12345