DETERMINATION OF THE CRYSTAL-STRUCTURE OF MO-2(V)P4O15

被引：16
|
作者：
COSTENTIN, G
LECLAIRE, A
BOREL, MM
GRANDIN, A
RAVEAU, B
机构：
[1] Laboratoire de Cristallographie et Sciences des Materiaux, 14050 Caen Cedex, Crismat, Ismra, Boulevard du Marechal Juin
来源：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1992年 / 201卷 / 1-2期
关键词：
MOLYBDENUM (V); MOLYBDENYL GROUP; P4O13 TETRAPHOSPHATE GROUPS; CRYSTAL STRUCTURE;
D O I：
10.1524/zkri.1992.201.1-2.53
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of a molybdenum tetraphosphate Mo2P4O15 has been determined from X-ray single crystal study in the monoclinic space group P2(1)/c (a = 8.3068(8), b = 6.5262(6), c = 10.718(1) angstrom, beta = 106.70(1)-degrees). Its structure consists of MoO6 octahedra sharing five of their corners with P4O13 tetraphosphate groups, the sixth one being free corresponds to a molybdenyl group.
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收藏
页码：53 / 58
页数：6
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