Bis[mu-3,5-bis(pyridin-2-yl)-1H-pyrazole]-bis[dibromidoiron(III)]

被引：1
|
作者：
Katsuta, Nagisa [1 ]
Mishima, Akio [1 ]
Fuyuhiro, Akira [2 ]
Hayami, Shinya [3 ]
Kawata, Satoshi [1 ]
机构：
[1] Fukuoka Univ, Fac Sci, Dept Chem, Jonan Ku, Fukuoka 8140180, Japan
[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
[3] Kumamoto Univ, Grad Sch Sci & Technol, Dept Chem, Kumamoto 8608555, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813026573
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title dinuclear complex, [Fe2Br4(C13H9N4) 2], which lies on an inversion center, features two approximately planar bis(pyridin-2-yl) pyrazole (bpypz(-)) ligands [maximum deviation = 0.082 (3) angstrom] and four bromide ions. Each Fe-III ion is octahedrally coordinated by four N atoms of two bpypz(-) ligands and two Br ions. pi-pi stacking interactions [centroid-centroid distances = 3.7004 (17)-4.0123 (18) angstrom] are observed between pyridyl and pyrazole rings, and between pyridyl and pyridyl rings of adjacent complex molecules.
引用
收藏
页码：M574 / +
页数：9
相关论文
共 50 条
  • [21] 2-[({[Bis(pyridin-2-yl) methylidene]hydrazinecarbonyl}hydrazinylidene)(pyridin-2-yl)methyl]pyridinium tetrafluoroborate
    Zhang, Jie
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1874 - U1531
  • [22] 2,2-Bis(pyridin-2-yl)-1,3-diazinane
    Haddad, Salim F.
    Warad, Ismail
    Jodeh, Shehdeh
    Ben Hadda, Taibi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O569 - +
  • [23] trans-Bis[3,5-bis(trifluoromethyl)-1H-pyrazole-κN2]dichloropalladium(II) monohydrate
    Spencer, Lara C.
    Guzei, Ilia A.
    Ojwach, Stephen O.
    Darkwa, James
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2006, 62 (09) : M421 - M423
  • [24] Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)]
    Chang, Hui-Chang
    Cole, Jacqueline M.
    Lin, Tze-Chia
    Sylvester, Sven O.
    Waddell, Paul G.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M690 - U490
  • [25] METAL-COMPLEXES OF 1,3-BIS(PYRIDIN-2-YL)PYRAZOLE - SPECTRAL, MAGNETIC AND STRUCTURAL STUDIES
    BAKER, AT
    CRAIG, DC
    DONG, G
    RAE, AD
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1995, 48 (06) : 1071 - 1079
  • [26] COPPER-COMPLEXES WITH A PYRAZOLE DERIVATIVE LIGAND - CRYSTAL-STRUCTURE OF TETRAKIS ([(3,5-BIS(PYRIDIN-2-YL)PYRAZOLATE)-(AQUA)COPPER(II)] NITRATE MONOHYDRATE)
    PONS, J
    LOPEZ, X
    CASABO, J
    TEIXIDOR, F
    CAUBET, A
    RIUS, J
    MIRAVITLLES, C
    INORGANICA CHIMICA ACTA, 1992, 195 (01) : 61 - 66
  • [27] Synthesis, X-ray structure, spectroscopic and magnetic properties of [bis(4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole-N′,N1)(aqua)copper(II)]bis(hydrogensulfate)
    van Koningsbruggen, PJ
    Goubitz, K
    Haasnoot, JG
    Reedijk, J
    INORGANICA CHIMICA ACTA, 1998, 268 (01) : 37 - 42
  • [28] 1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetrafluoridoborate
    Grieco, Gabriele
    Blacque, Olivier
    Berke, Heinz
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2066 - U805
  • [29] Syntheses and characterization of dimeric metal complexes of 3,5-bis[bis(N-6-pivalamido-2-pyridylmethyl)aminomethyl]-1H-pyrazole containing intramolecular hydrogen bonding networks
    Ng, Kwanyi
    Ziller, Joseph W.
    Borovik, Andrew S.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [30] Preparation, Electronic Properties, and Powder-XRD Structure Analysis of 3,5-Bis(pyridin-2-yl)-H-1,2,4-triazoledichloridocopper(II)
    Sugiyarto, Kristian Handoyo
    Yunita, Isti
    Goodwin, Harold Andrew
    INDONESIAN JOURNAL OF CHEMISTRY, 2020, 20 (06) : 1422 - +
12345